Amazing Spider-Man #45/486 (2002)

"Until the Stars Turn Cold," script by J. Michael Straczynski, art/cover by John Romita, Jr., inks by Scott Hanna.

As Spider-Man steadily digs himself out of the hotel's rubble, Carlyle goes to the movie studio where he bursts onto the Lobster Man set. He takes hostages and decides to kill May so people will take him seriously.  However, Dr. Octopus rescues May and renews his attack on Carlyle. Spidey arrives as Ock falls, but just in time to tell Spidey he made a crack in Carlyle's armor.  Spidey finds the crack and fills it with web-fluid, gumming up the suit, causing it to freeze up.  Dr. Octopus escapes in the chaos. Later, Mary Jane tells Peter she still needs time on her own; he promises to wait as long as it takes.

Near mint condition.